Barcelona's Liga Iberdrola title dreams were ended after they were defeated 1-0 by Tenerife at the Estadio La Palmera on Sunday.
Heading to Tenerife, the Blaugrana needed a win while with hoping for Atletico Madrid to slip at Real Sociedad on the same day.
After a scoreless first half, Cameroon international Raissa Feudjio teed up Maria Jose to score in the 56th minute for what turned out to be the match-winner.
With Barcelona's defeat, Esther Gonzalez's hat-trick ensured Atletico claimed a 3-1 win at Estadio Zubieta XXI and emerged champions for the third sucessive season.