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WATCH LIVE: Neymar, loaded hosts Brazil open Olympics versus South Africa

Neymar gets his first chance to influence a major international tournament this summer when hosts Brazil face-off with South Africa at what’s sure to be an electric Estádio Nacional Mané Garrincha in Brasília on Thursday.

The 3 p.m. EDT kickoff sees the Barcelona star and his tournament favorite side open play in its group, three hours after Iraq and Denmark got Group A started.

WATCH: Brazil vs. South Africa at NBCOlympics.com

In addition to Neymar, there’s his Barca teammate Rafinha and Lazio standout Felipe Anderson. The side will be buoyed in the back by Paris Saint-Germain mainstay Marquinhos, and new Manchester City man Gabriel Jesus joins “Gabigol” of Santos as a dangerous young combination in attack.