The ECHO understands that the Reds are in talks with a number of potential opponents for the midweek game in early August.
Jürgen Klopp's side rounded off their preparations for the current campaign in similar fashion last summer when they hosted Torino.
Liverpool also remain in discussions to play a lucrative friendly at Tottenham's new stadium in late July.
Wembley and Dublin's Aviva Stadium have been used previously but this time around they aren't available. With Liverpool also unable to use Cardiff's Millennium Stadium, Tottenham’s new home emerged as an option with Napoli likely to provide the opposition.