The 27-year-old will become the second member of the first-team squad to take up a coaching role, with midfielder Christie Murray already coaching the U14s.
Jane made the switch to the Reds this summer after seven years at Reading, where she had already started her coaching journey at their RTC.
At Liverpool, she will coach the U11 age group alongside Luke Butterworth and got the chance to meet the team earlier this week, alongside first-team manager Vicky Jepson.
The pair met players from the U9s, U10s, U11s and U12s groups before overseeing and taking part in the U11s training session.