The Azzurri have shown a capacity to handle the pressure of the 12-yard battle of wits, but what's their overall record like?
Italy are one of the most successful teams in international football, with a long history of competing at the business end of major tournaments.
They have competed in their fair share of penalty shootouts along the way and have even had to make the dreaded walk in two World Cup finals.
Goal brings you all the details about Italy's penalty shootout record, who they have won and lost against, and when.