The centre-back returns from injury in defence in place of Jordan Henderson, who is ruled out due to a minor fitness issue.
Elsewhere, Divock Origi and Alex Oxlade-Chamberlain come in for Mohamed Salah and Roberto Firmino as a trio of alterations are made to the team deployed against Manchester United on Sunday.
Kostas Tsimikas is back among the substitutes after a knee problem. Georginio Wijnaldum captains the side.
Liverpool: Alisson, Alexander-Arnold, Fabinho, Matip, Robertson, Thiago, Wijnaldum, Oxlade-Chamberlain, Shaqiri, Mane, Origi.
Subs: Kelleher, Milner, Firmino, Salah, Jones, Minamino, Tsimikas, Phillips, N. Williams.