The 19-year-old replaces Andy Robertson in one of four changes made by the champions from Sunday’s win over Aston Villa.
Jordan Henderson, Georginio Wijnaldum and Roberto Firmino also return, while James Milner is back on the bench.
Liverpool: Alisson, Alexander-Arnold, Gomez, Van Dijk, Williams, Henderson, Wijnaldum, Keita, Oxlade-Chamberlain, Salah, Firmino.
Subs: Adrian, Fabinho, Milner, Mane, Minamino, Robertson, Origi, Jones, Elliott.
